Chinese Science Bulletin 2008, 53(21) 3341-3345 DOI:   10.1007/s11434-008-0407-1  ISSN: 1001-6538 CN: 11-1785/N

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Keywords
xieite
chromite
high-pressure
polymorph
new mineral
shock
Suizhou meteorite
Authors
CHEN Ming
SHU JinFu
MAO Ho-kwang
PubMed
Article by CHEN Ming
Article by SHU JinFu
Article by MAO Ho-kwang

Xieite, a new mineral of high-pressure FeCr2O4 polymorph

CHEN Ming1, SHU JinFu2 & MAO Ho-kwang2

1 Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;
2 Geophysical Laboratory, Carnegie Institution of Washington, 5251 Broad Branch Road, NW, 20015 Washington, DC, USA

Abstract

Xieite, a new mineral, occurs in the shock vein of the Suizhou meteorite. The mineral has an orthorhombic structure and its space group is Bbmm. The cell parameters are a = 9.462(6) Å, b = 9.562(9) Å, c = 2.916(1)Å. The crystal-chemical formula is (Fe0.87Mg0.13Mn0.01)1.01(Cr1.62Al0.25Ti0.08V0.02)1.97O4, or simply formula FeCr2O4. Stronger X-ray diffraction lines are [d (Å), I/Io]: (2.675, 100), (2.389, 20), (2.089, 10), (1.953, 90), (1.566, 60), (1.439, 15), (1.425, 15), (1.337, 40). Xieite is a high pressure polymorph of FeCr2O4 and formed by solid-state transformation of chromite under shock-induced high pressure and temperature, in association with other high-pressure minerals including ringwoodite, majorite, lingunite and tuite. The P-T condition for the formation of xieite is estimated to be 18―23 GPa and 1800―1950℃, respectively. Xieite has recently been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (IMA 2007-056). The mineral name, xieite, is named after Xiande Xie.

Keywords xieite   chromite   high-pressure   polymorph   new mineral   shock   Suizhou meteorite  
Received 2008-06-02 Revised 2008-07-23 Online:  
DOI: 10.1007/s11434-008-0407-1
Fund:

Supported by National Natural Science Foundation of China (Grant Nos. 40672035 and 40272028), and the Chinese Academy of Sciences (Grant No. KJCX2-SW-N20)

Corresponding Authors: CHEN Ming
Email: mchen@gig.ac.cn
About author:

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